Friday, November 30, 2012

Like Dissolves Like Millions of Miles Away

One of the main reasons scientists study space is to find signs of life on other celestial bodies. This is also the basis for why Mars gets so much attention. Out of all the celestial bodies known to us, it is the one most likely to contain life. The reason why Mars has the possibility of containing life is that it has a strong possibility of having water on its surface. Water is considered the most essential part for life to exist for a few reasons. For one, every organism on Earth needs water to survive. Another reason is that all of the organic compounds that make of living things work well with water.

This makes sense because most of the organic compounds that are necessary for life are polar, such as glucose. Even some of the compounds that are not polar have high molar masses. Due to their high molar mass, these compounds have large London Dispersion Forces (LDF). Solubility of molecules depends on their intermolecular forces (IMF). Solvents with high IMFs dissolve solutes with high IMFs and vice versa; this is the “like dissolves like” rule. This why water, a polar molecule, can dissolve all of the organic compounds that organisms need to break down for food. What if organisms used compounds and solvents with lower IMFs?


New research about Titan, Saturn’s moon, proposes this same theory. Titan contains liquid and gaseous methane in its atmosphere and on parts of its surface. Scientist proposed a theory stating that there is a possibility that organisms on Titan could use methane as their organic solvent instead of water. Since methane is nonpolar and has a low LDF, compounds that are nonpolar and have low LDFs would be needed for the methane to be useful. Acetylene is a compound that scientist believe could be used in place on glucose if this theory were proven true. Since, this follows the “like dissolves like” rule, this concept is quite plausible.

Monday, November 26, 2012

Does the type of ice even matter?

Unlike what many people believe, Mars is actually very similar to Earth. Mars also have polar ice caps, which get bigger and smaller in accordance to the seasons. These seasonal polar caps are made from the martian air that freezes during the winter. They are made out of frozen carbon dioxide, or "dry ice." So why are these caps made out of carbon dioxide? Why not water?
Answering this question seems very simple. For one thing, the atmosphere of Mars is 95 percent carbon dioxide. That means that when the air freezes during the winter, the gaseous carbon dioxide is converted in solid carbon dioxide and stored in the polar caps. Depending on the time of year, more than a quarter of the atmosphere can be found frozen on the ground in these caps. 
But is that really the only answer? We can dive a little deeper into chemistry to fully answer this question. 
Carbon dioxide has a low boiling point. This is because the only intermolecular force in carbon dioxide is London Dispersion Forces, or LDF. It does not have dipole dipole interactions because of the structure's symmetry, nor hydrogen bonding, because it is a nonpolar molecule. Therefore, it does not require much energy to separate carbon dioxide molecules from the solid state to gas state. It would take low amounts of energy and low temperatures to have dry ice, and these measurements are found conveniently on Mars.
Maybe you already knew that carbon dioxide has only low LDF. But did you ever think to connect that simple idea to the polar ice cap cycle existing on Mars? These simple connections can easily be made, if you just look for them throughout the universe. 

Wednesday, November 21, 2012

Atmosphere of Saturn


If you look across the skyline of American cities, this sight is not very uncommon. It seems like there is smoke coming out of these buildings, corporations, and factories. After all, they are called smokestacks. In fact, you would not be too far off to say that this is smoke. Smoke is a collection of tiny solid, liquid, and gas particles. But what you see in this picture is a specific form of smoke known as smog. Smog might not be as familiar to the average person. 


This cycle shows how smog is produced
Smog is created by the many pollutants in our atmosphere creating ozone, and reacting with light. Refineries, factories, chemical plants, and the burning of fossil fuels for car engines produces volatile organic compounds like acetone, benzene, formaldehyde, etc. , sulfur. and nitrogen oxides. This in turn makes ozone. While we regularly hear of ozone as the layer in the atmosphere protecting the earth from the ultraviolet rays of the sun, ground level ozone can be quite dangerous. The ground level ozone can be the cause of breathing problems, asthma, reduced resistance to lung infections and colds, and eye irritation. It can even inhibit plant growth and cause terrible damage to crops and forests. Smog is most visible as the morning haze we sometimes might see in the morning or "smoke and fog". 



Saturn's aurora in Ultraviolet from Hubble.Credits: J.T. Trauger (Jet Propulsion Laboratory) and NASA.
An actual picture of Saturn
We know that tons and tons of pollutants are being released into the atmosphere, but a lot of the time don't even bother to think twice about it. Well here is a simple reason why we should put a lot more focus on the way we treat Earth: The picture above is a picture of Saturn. One of the first questions you might have is why Saturn is such a weird color? While Earth is approximately 79% Nitrogen and 21% Oxygen, Saturn is 75% Hydrogen and 25% Helium. But in the atmosphere of Saturn there are trace amounts of nitrogen, oxygen, and sulfur. Why is this such a big deal? Surrounding Saturn is a layer of smog! Even with such small amounts of nitrogen, oxygen, and sulfur, the majority of the planet is covered in a film of it. It is almost scary to think that a layer of this nasty gunk is slowly building up on Earth and might destroy the beautiful blues and greens we think of when we look at a picture of Earth. Looking back at the picture at the top, a grayish Earth just might already be here...

Thursday, November 15, 2012

The Atmosphere of Mars

The atmosphere of planets is an important variable that drastically affects the surfaces. For example, since the atmosphere of Venus is so thick, Venus is a barren and burning planet. The Earth's atmosphere is a vital factor to life on earth. Neptune is blue because of the composition of its atmosphere, mostly methane, and has storms up to 2,400 km/hr, the fastest winds in out of all the planets.
The Planets and Pluto. Not to scale.
Mars in particular has a thin atmosphere. It is 100 times thinner than that of Earth and composed of 95.3 percent carbon dioxide, 2.7 percent nitrogen, 1.6 percent argon, .13 percent oxygen, and .08 percent carbon monoxide, with trace amounts of water, nitrogen oxide, neon, hydrogen-deuterium-oxygen, krypton and xenon. The atmosphere is thick enough to support weather, clouds, and winds. Seasonally, the density of the atmosphere changes because the carbon dioxide freezes out of the air in the winter. Mars also has the largest dust storms in the solar system, capable of blanketing the entire planet for months. These dust storms occur because the airborne dust absorbs sunlight, which warms the surrounding atmosphere, causing warmers air to flow to colder regions, generating winds; gradually strong winds lift dust off the ground, creating huge dust storms.
Two images taken by the Hubble Space Telescope showing Mars before (left) and during (right) the great Martian dust storm of 2001. 
Some scientists believe that at one point in history, Mars had a thicker atmosphere, cloudy skies, and liquid water flowing on the surface. But then, throughout its history, a process called sputtering would have knocked away atoms from its atmosphere through impacts from energetic particles. This video explains the process. 
It is interesting to see that while Mars and Earth look drastically different, in the past Mars might have just been like the Earth of the present, capable of housing life. This is what the hopes of many scientists lie on, the chance that Mars will once again be able to house life. While it might seem like a scene straight out of a sci-fi movie, life on mars might not be in the too distant future. 

Sunday, November 11, 2012

The Soil of Mars


Many people wonder what it would be like to step foot on Mars. Many people also wonder if the terrain of Mars could support life. With the help of recent discoveries by NASA’s Curiosity Rover, we are one step closer to finding out. Currently the Curiosity Rover is located in a region of Mars called “Rocknest.”

 Wind-Blown Martian Sand
(Left) This image shows “Rocknest” as it would look on Mars.
 (Right) This image shows“Rocknest” under lighting conditions on Earth.

The rover took a sample of soil from this region. The sample was analyzed with its Chemistry and Mineralogy instrument, as known as CheMin for short. The CheMin uses an Alpha Particle X-Ray Spectrometer (APXS) in order to analyze samples. The CheMin shoots X-Rays at a sample of soil, and using a method called X-Ray defraction. They use X-Ray diffraction because each mineral has a distinct interaction with X-Rays. Using this method not only determines what minerals are in the soil, but also how abundant they are.

 First X-ray View of Martian Soil
This image shows how X-Ray defraction works. Each ring represents a mineral and its abundance.
For a better understanding of how the CheMin works, check out this video:

This was the first sample the rover took. Part of the soil was determined to be basaltic and alkalic material. These materials are similarto the minerals found in Hawaii and other volcanic areas. This is expected because Mars is one of the most actively volcanic celestial bodies in our solar system. Some of the materials discovered include volcanic glass, silicon, aluminum, sodium, and potassium. Most of these materials are thought to have been formedthrough the breakdown of rocks by water, an essential part of determining if a planet can contain life. However, there are other processes that could break these rocks down, so scientists are not jumping to any conclusions.

Although all of this is preliminary, scientists are very optimistic about future tests.

Wednesday, November 7, 2012

The Ringed Planet

Astronomers have been looking up into the sky for ages. Ancients could see what appeared to be five distinct planets revolving around our very own Earth. One of the more recent astronomers, Galileo, had his curiosity spiked in a planet that had three celestial bodies connected together, the middle being the largest.  Could nature really allow such a monstrosity to take part in the great sky above? Even with telescopes, the planet seemed so small and very distant.

Years later, we know the planets revolve around the sun, and the three headed beast in the sky is really Saturn surrounded by its rings. And yet besides this, there is still so little we know about Saturn and its rings. Saturn's rings are actually made of a multitude of particles that range in size that revolve around Saturn due to its gravitational pull. However, these particles that make up the rings can stretch out up to hundreds and thousands of kilometers! What makes Saturn so interesting is that the rings are made out of ice and some types of rock. Since we know water is the beginning of life, it is no surprise that scientists are very intrigued about life on Saturn and its surrounding moons.


From the pictures you see of Saturn, you might think Saturn only has a couple of very large rings. Wrong! Saturn has thousands of tiny ringlets. Who would've known! But besides this, Saturn's rings have gaps in them. Some of Saturn's moons like Mimas have a large enough mass to affect some of the particles by its gravity. The gravity of the moons yank the particles out of the rings. And all of this is only the beginning of Saturn. The actual planet Saturn has many secrets that just need to be explored!